Developments in Polymer Degradation: v. 4 reading book online legal |

Polymer degradation is a change in the properties—tensile strength, color, shape, etc.—of a polymer or polymer-based product under the influence of one or more environmental factors such as heat, light or chemicals such as acids, alkalis and some salts.These changes are usually undesirable, such as cracking and chemical disintegration of products or, more rarely, desirable, as in. Polymer Degradation. Polymer degradation includes all changes in both the chemical structure and physical properties of polymers or polymer-based products that lead to the loss of properties such as tensile strength, color, shape, etc., under the influence of processing conditions, or one or more environmental factors e.g., heat, light, or exposure to chemicals Hawkins, 1984b. However polymer degradations which fit “autocatalytic” mass loss kinetics may well yield a first order kinetics fit when the degradation is measured by change in degree of polymerization DP e.g., light scattering, osmotic pressure, viscosity, etc. or by changes in functional group concentration e.g., infra red analysis.These methods measure chain scission as shown in Eq. Polymer Degradation and Stability deals with the degradation reactions and their control which are a major preoccupation of practitioners of the many and diverse aspects of modern polymer technology. Deteriorative reactions occur during processing, when polymers are subjected to heat, oxygen and mechanical stress, and during the useful life of the materials when oxygen and sunlight are the.

Developments in polymer characterisation—5: Edited by J. V. Dawkins, Elsevier Applied Science Publishers, London and New York, 1986, x343 pp. Price £38·00 James N. Hay Pages 360-362. The study of polymer degradation and stabilisation is of considerable practical importance as the industrial uses of polymeric materials continue to expand. In this book, the authors lucidly relate technological phenomena to the chemistry and physics of degradation and stabilisation processes. While degradation of P33 to D33 was complete in ca. 24 h with 5 equivalents of trifluoroacetic acid per repeat unit, degradation of P31 to D31 occurred in less than 10 min with ca. 0.6 equivalents of HCl per repeat unit, presumably due to the more sensitive hemiaminal ether in the backbone and aromatization of the heterocycle serving as a. Summary. Thermal degradation processes occurring in the most common condensation polymers are examined. It is remarked that the inclusion of functional groups into a polymer chain lowers the importance of decomposition reactions involving free radical and multiple hydrogen-transfer processes. N. Grassie, A. Johnston, A. Scotney, Thermal degradation of bromine containing polymers—Part 4: Mechanisms of decomposition of copolymers of 2-bromoethyl methacrylate and methyl acrylate and blends of the homopolymers, Polymer Degradation and Stability, 10.1016/0141-39108190017-3, 3, 6, 453-468, 1981.

Feb 24, 2007 · 1981. New Developments in Degradation and Stabilization of Polymers Based on Vinyl Chloride. Journal of Macromolecular Science, Part C: Vol. 20, No. 2, pp. 243-308. Developments in Polymer Characterisation—4. Editors: Dawkins, J.V. Ed. Free Preview. Buy this book eBook 53,49 € price for Spain gross Buy eBook ISBN 978-94-009-6628-4; Digitally watermarked, DRM-free; Included format: PDF; ebooks can be used on all reading devices.

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